Organic Chemistry

Cycloaddition Reactions in Organic Synthesis by W. Carruthers

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By W. Carruthers

Demonstrates the broad scope of cycloaddition reactions, together with the Diels-Alder response, the ene response, 1,3-dipolar cycloadditions and [2+2] cycloadditions in natural synthesis. the writer, a number one exponent of the topic, illustrates the ways that they are often hired within the synthesis of quite a lot of carbocyclic and heterocyclic compounds, together with quite a few common items of varied forms. designated realization is given to intramolecular reactions, which frequently offer a quick and effective path to polycyclic compounds, and to the stereochemistry of the reactions, together with fresh and constructing paintings on enantioselective synthesis.

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05 equiv. 1 equiv. 1 equiv. 1 equiv. 1 equiv. 1 equiv. 1 equiv. 1 equiv. 2 equiv. 05 equiv. 1 equiv. 1 equiv. 1 equiv. 2 equiv. 2 equiv. 05 equiv. 1 equiv. 05 equiv. 05 equiv. 05 equiv. 05 equiv. 05 equiv. 05 equiv. 05 equiv. –20 8C, 20 h 83%, 2 : 98 97% ee For each reaction the data given are: Amount of catalyst; Temperature, time; Yield, endo/exo; and Optical yield. 05 equiv. 05 equiv. 05 equiv. 5 Appendix 51 52 1 Catalytic Asymmetric Diels-Alder Reactions Fig. 10 References Fig. 11 Acknowledgment I would like to thank Professors E.

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